Ozturk, Turan, Rice, Craig R., Wallis, John D. (1995) Synthesis of a chiral monosubstituted derivative of bis(ethylenedithio)tetrathiafulvalene: reaction of the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol with 2-thioxo-1,3-dithiole-4,5-dithiolate. Journal of Materials Chemistry, 5 (10). pp. 1553-1556. ISSN 0959-9428. (doi:10.1039/jm9950501553) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:19431)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1039/jm9950501553 |
Abstract
2-Thioxo-1,3-dithiole-4 5-dithiolate reacts stereospecifically with the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol by two nucleophilic attacks, ring opening of the cyclic sulfate ester at carbon and displacement of the nearer fluorine atom, to form a derivative of the 1,3-dithiolo[4,5-b]-1,4-dithiin ring system. This product is converted in two steps into an analogue of bis(ethylenedithio)tetrathiafulvalene with a 2-fluoro-1-hydroxyethyl side-chain, a new substrate for the preparation of electroactive materials.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/jm9950501553 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Biosciences |
| Depositing User: | O.O. Odanye |
| Date Deposited: | 01 Jun 2009 19:56 UTC |
| Last Modified: | 05 Nov 2024 09:56 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/19431 (The current URI for this page, for reference purposes) |
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