Wiseman, Andrew J., Jones, Richard G., Swain, Anthony C., Went, Michael J. (1996) Synthesis and characterization of tricarbonymolybdenum-functionalized poly(methylphenylsilane). Polymer, 37 (25). pp. 5727-5733. ISSN 0032-3861. (doi:10.1016/S0032-3861(96)00410-7) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:18586)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/S0032-3861(96)00410-7 |
Abstract
The synthesis and characterization of a new metal-functionalized polysilane is reported. Treatment of poly(methylphenylsilane) with Mo(CO)(3)(NC5H5)(3) and BF3.OEt(2) affords the novel copolymer, poly(methylphenylsilane-stat-methyl (eta(6)-phenyltricarbonylmolybdenum)silane). The synthesis and characterization of the model compounds, (eta(6)-phenyltricarbonylmolybdenum)trimethylsilane, 1-phenyl-2-(eta(6)-phenyltricarbonylmolybdenum)tetramethyldisilane and 1,2-di(eta(6)-phenyltricarbonylmolybdenum)tetramethyldisilane, are used to support a full structural characterization of the copolymer. Copyright (C) 1996 Elsevier Science Ltd.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/S0032-3861(96)00410-7 |
| Uncontrolled keywords: | polysilanes; functionalization; molybdenumtricarbonyl |
| Subjects: | Q Science > Q Science (General) |
| Divisions: | Divisions > Directorate of Education > School of Education |
| Depositing User: | P. Ogbuji |
| Date Deposited: | 28 Apr 2009 18:05 UTC |
| Last Modified: | 05 Nov 2024 09:54 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/18586 (The current URI for this page, for reference purposes) |
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