Intramolecular interactions in ethyl bis-(2,4-dinitrophenyl)acetate

Ertas, Erdal, Ozturk, Turan, Wallis, John D., Watson, William H. (1998) Intramolecular interactions in ethyl bis-(2,4-dinitrophenyl)acetate. Journal of Chemical Crystallography, 28 (5). pp. 409-412. ISSN 1074-1542. (doi:10.1023/A:1022472427510) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:17714)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: http://dx.doi.org/10.1023/A:1022472427510

Abstract

The crystal structure of ethyl bis(2,4-dinitrophenyl)acetate, determined by room temperature X-ray diffraction, shows that this crowded molecule contains two short intramolecular interactions between nitro oxygen atoms and electron deficient carbon atoms. One mimics an early stage of the nucleophilic addition to a carbonyl group (O ... C, 2.730 Angstrom), and the other mimics an early stage of a Michael reaction (O ... C, 2.854 Angstrom). Crystal data: C16H12N4O10, M-r = 420.29, a = 10.079(1), b = 11.139(1), c = 16.162(1) Angstrom, beta = 91.319(7)degrees, monoclinic, P2(1)/c, Z = 4.

Item Type:	Article
DOI/Identification number:	10.1023/A:1022472427510
Subjects:	Q Science > QC Physics
Divisions:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	R.F. Xu
Date Deposited:	26 Jun 2009 11:20 UTC
Last Modified:	05 Nov 2024 09:53 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/17714 (The current URI for this page, for reference purposes)

University of Kent Author Information

Wallis, John D..

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