Davidson, R. Stephen, Hageman, Hendrik J., Lewis, Sandralee P. (1998) The synthesis and characterization of some polymeric Type-1 photoinitiators based on alpha-hydroxymethylbenzoin and alpha-hydroxymethylbenzoin methyl ether. Journal of Photochemistry and Photobiology a-Chemistry, 116 (3). pp. 257-63. ISSN 1010-6030. (doi:10.1016/S1010-6030(98)00276-7) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:17679)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/S1010-6030(98)00276-7 |
Abstract
The acrylic and methacrylic esters of alpha-hydroxymethylbenzoin and alpha-hydroxymethylbenzoin methyl ether, respectively, are synthesized and thermally copolymerized with methyl acrylate and methyl methacrylate using a chain transfer agent in some cases to control the molecular weight of the copolymers. The products are characterized by H-1 NMR spectroscopy and UV-absorption spectroscopy. Certain copolymers exhibited hyperchromism. The photodecomposition of the copolymers in the presence of suitable radical trapping agents shows their potential as photoinitiators.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/S1010-6030(98)00276-7 |
| Uncontrolled keywords: | alpha-hydroxymethylbenzoin (meth)acrylate; polymeric Type-1 photoinitiators |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | I. Ghose |
| Date Deposited: | 01 Apr 2009 18:51 UTC |
| Last Modified: | 16 Nov 2021 09:55 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/17679 (The current URI for this page, for reference purposes) |
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