Synthesis and characterization of poly(methylphenylsilylene) poly(methyl methacrylate) block copolymers

Lutsen, Laurence, Jones, Richard G. (1998) Synthesis and characterization of poly(methylphenylsilylene) poly(methyl methacrylate) block copolymers. Polymer International, 46 (1). pp. 3-10. ISSN 0959-8103. (doi:10.1002/(sici)1097-0126(199805)46:1<3::aid-pi915>3.0.co;2-x) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:17429)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: https://doi.org/10.1002/(sici)1097-0126(199805)46:...
Additional URLs: http://www3.interscience.wiley.com/journ...

Abstract

Block copolymers of poly(methylphenylsilylene) and poly(methyl methacrylate) have been synthesized by condensation of alpha,omega-dichloropoly(methylphenylsilylene) with poly(methyl methacrylate)-lithium. The alpha,omega-dichloropoly(methylphenylsilylene) was synthesized by the Wurtz-type reductive coupling of dichloromethylphenylsilane using sodium in boiling toluene and poly(methyl methacrylate)-lithium was prepared by anionic polymerization of methyl methacrylate in tetrahydrofuran initiated by alpha-methylstyrene-lithium/LiCl. The structures of the block copolymers have been confirmed using size exclusion chromatography and NMR spectroscopy. (C) 1998 SCI.

Item Type:	Article
DOI/Identification number:	10.1002/(sici)1097-0126(199805)46:1<3::aid-pi915>3.0.co;2-x
Additional information:	Special Issue: First Reports from the ARPEGE Network
Uncontrolled keywords:	poly(methylphenylsilylene); poly(methyl methacrylate); block copolymer
Subjects:	Q Science
Institutional Unit:	Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy
Former Institutional Unit:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	M.A. Ziai
Date Deposited:	03 Apr 2009 00:28 UTC
Last Modified:	20 May 2025 09:32 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/17429 (The current URI for this page, for reference purposes)

University of Kent Author Information

Jones, Richard G..

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