Bell, Paul C. and Wallis, John D. (1999) Addition of nucleophiles to electron-deficient alkenes: structural studies on the incipient reaction and the zwitterionic intermediate. Chemical Communications (3). pp. 257-258. ISSN 1359-7345. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)
Three distinct interactions between a Me2N group and an electron-deficient alkene located in the peri positions of a naphthalene ring comprise an almost complete cyclisation, an incipient reaction, and a less favourable orientation of the nitrogen lone pair with respect to the alkene, which can be related to the electronic characteristics of the alkene substituents; the cyclised material is zwitterionic and is composed of the enolate of a beta-dicarboxylic diester and a trialkylarylammonium cation.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Physical Sciences|
|Depositing User:||M. Nasiriavanaki|
|Date Deposited:||13 Jul 2009 07:30|
|Last Modified:||17 Jun 2014 11:30|
|Resource URI:||https://kar.kent.ac.uk/id/eprint/17067 (The current URI for this page, for reference purposes)|