Bell, Paul C., Wallis, John D. (1999) Addition of nucleophiles to electron-deficient alkenes: structural studies on the incipient reaction and the zwitterionic intermediate. Chemical Communications, (3). pp. 257-258. ISSN 1359-7345. (doi:10.1039/a808488b) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:17067)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1039/a808488b |
Abstract
Three distinct interactions between a Me2N group and an electron-deficient alkene located in the peri positions of a naphthalene ring comprise an almost complete cyclisation, an incipient reaction, and a less favourable orientation of the nitrogen lone pair with respect to the alkene, which can be related to the electronic characteristics of the alkene substituents; the cyclised material is zwitterionic and is composed of the enolate of a beta-dicarboxylic diester and a trialkylarylammonium cation.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/a808488b |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | M. Nasiriavanaki |
| Date Deposited: | 13 Jul 2009 07:30 UTC |
| Last Modified: | 16 Nov 2021 09:55 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/17067 (The current URI for this page, for reference purposes) |
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