Burkholder, Eric, Heirtzler, Fenton R., Orian, Laura, Ouellette, Wayne, Zubieta, Jon (2008) Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex. Polyhedron, 27 (18). pp. 3700-3702. ISSN 0277-5387. (doi:10.1016/j.poly.2008.09.007) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:14853)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/j.poly.2008.09.007 |
Abstract
Hydrothermal treatment of 2,3-bis(2',6"-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2'-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material. and scalar relativistic ZORA DFT modeling of the complex dication are presented.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/j.poly.2008.09.007 |
| Uncontrolled keywords: | Macrocycle Structure Copper Hydrothermal Molybdenum |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | Suzanne Duffy |
| Date Deposited: | 04 Feb 2009 12:54 UTC |
| Last Modified: | 05 Nov 2024 09:49 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/14853 (The current URI for this page, for reference purposes) |
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