Maji, Subrata, Gupta, Prachi, Clowes, Rob, Matsushita, Yoshitaka, Shrestha, Lok Kumar, Slater, Anna G., Hill, Jonathan P., Chahal, Mandeep K. (2026) Central-metal-cation-based modulation of gas adsorption selectivity in porous tetrapyrrolic materials. Chemical Communications, . ISSN 1364-548X. (doi:10.1039/d5cc06796k) (KAR id:113136)
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| Official URL: https://doi.org/10.1039/d5cc06796k |
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Abstract
We present a direct strategy to assemble porous tetrapyrrolic materials with tunable gas uptake selectivity by varying the coordinated cation. Co-OX1 shows improved CO2 uptake of 51.66 cm3 g−1 at 298 K, while free base-OX1 demonstrates a CO2/N2 selectivity of 202.9. This approach offers a viable route to CO2 capture technologies.
| Item Type: | Article |
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| DOI/Identification number: | 10.1039/d5cc06796k |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Natural Sciences > Chemistry and Forensic Science |
| Former Institutional Unit: |
There are no former institutional units.
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| Funders: | University of Kent (https://ror.org/00xkeyj56) |
| SWORD Depositor: | JISC Publications Router |
| Depositing User: | JISC Publications Router |
| Date Deposited: | 24 Feb 2026 11:16 UTC |
| Last Modified: | 25 Feb 2026 11:07 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/113136 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Chahal, Mandeep K..
| Creator's ORCID: |
 https://orcid.org/0000-0002-8810-2196
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