He, Yiyi, Souza, Cauê P., Weiser, Jonas, Dietz, Maximilian, Krummenacher, Ivo, Dewhurst, Rian D., Braunschweig, Holger, Fantuzzi, Felipe, Cui, Jingjing (2024) Single electron oxidation, chloride abstraction, and hydride-induced decomposition of a dichloro-bis(germylene). European Journal of Inorganic Chemistry, . Article Number e202400422. ISSN 1434-1948. E-ISSN 1099-0682. (doi:10.1002/ejic.202400422) (KAR id:107276)
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| Official URL: https://doi.org/10.1002/ejic.202400422 |
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Abstract
In this work we explore the reactivity of a dichloro-bis(germylene) compound that features a naphthyridine diimine (NDI) ligand, denoted NDI-Ge 2Cl2. Upon reaction with the oxidant [Cp2Fe][BArF4] (Cp = C5H5, BArF4 = [{3,5-(CF3)2C6H3}4B]), we observed the formation of the radical species [NDI-Ge2Cl2]•+[BArF4]−. Furthermore, the introduction of Na[BArF4] induced a single chloride anion abstraction process, resulting in the formation of [NDI-Ge2Cl][BArF4]. The addition of Li[HB(sBu)3] to NDI-Ge2Cl2 led to the generation of NDI-Ge, presumably via a Cl/H exchange pathway followed by a decomposition process.
| Item Type: | Article |
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| DOI/Identification number: | 10.1002/ejic.202400422 |
| Uncontrolled keywords: | Single-electron oxidation: Chloride abstraction; Bis-germylene; Radical cation |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: |
Engineering and Physical Sciences Research Council (https://ror.org/0439y7842)
European Cooperation in Science and Technology (https://ror.org/01bstzn19) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 19 Sep 2024 16:53 UTC |
| Last Modified: | 11 Nov 2024 10:22 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/107276 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Souza, Cauê P..
| Creator's ORCID: |
 https://orcid.org/0000-0001-5545-004X
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| CReDIT Contributor Roles: |
Fantuzzi, Felipe.
| Creator's ORCID: |
https://orcid.org/0000-0002-8200-8262
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| CReDIT Contributor Roles: |
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