Audsley, Gabrielle, Carpentier, Ambre, Pécharman, Anne-Frédérique, Wright, James, Roseveare, Thomas M., Clark, Ewan R., Macgregor, Stuart A., Riddlestone, Ian M. (2024) Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)2] to form unsupported Ni-boryls. Chemical communications, 60 (7). pp. 874-877. ISSN 1364-548X. E-ISSN 1364-548X. (doi:10.1039/D3CC05369E) (KAR id:104459)
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| Official URL: https://doi.org/10.1039/D3CC05369E |
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Abstract
[Ni(IMes)2] reacts with chloroboranes via oxidative addition to form rare unsupported Ni-boryls. In contrast, the oxidative addition of hydridoboranes is not observed and products from competing reaction pathways are identified. Computational studies relate these differences to the mechanism of oxidative addition: B–Cl activation proceeds via nucleophilic displacement of Cl−, while B–H activation would entail high energy concerted bond cleavage.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/D3CC05369E |
| Uncontrolled keywords: | chloroboranes; Ni-borylis; hydridoboranes; nucleophilic displacement |
| Subjects: |
Q Science > QC Physics Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: | University of Kent (https://ror.org/00xkeyj56) |
| Depositing User: | Ewan Clark |
| Date Deposited: | 02 Jan 2024 14:37 UTC |
| Last Modified: | 16 Feb 2024 15:15 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/104459 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Clark, Ewan R..
| Creator's ORCID: |
 https://orcid.org/0000-0001-7287-2631
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