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Stepwise and selective synthesis of chelating, multimetallic and mixed-metal π-diborene complexes

Duwe, Dario, Saha, Koushik, Endres, Lukas, Brückner, Tobias, Dewhurst, Rian D., Dietz, Maximilian, Radacki, Krzysztof, Fantuzzi, Felipe, Braunschweig, Holger (2024) Stepwise and selective synthesis of chelating, multimetallic and mixed-metal π-diborene complexes. Chemical Communications, 60 (9). pp. 1120-1123. ISSN 1359-7345. (doi:10.1039/D3CC05477B) (KAR id:104384)

Abstract

The reaction of a pyridyl-substituted, doubly Lewis base-stabilised diborene with different amounts of copper(I) precursors led to the formation of the first chelating π-diborene complexes, the first π-diborene complexes in which metals are bound to both faces of the B=B bond, and the first mixed-metal π-diborene species.

Item Type: Article
DOI/Identification number: 10.1039/D3CC05477B
Uncontrolled keywords: Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders: European Research Council (https://ror.org/0472cxd90)
Deutsche Forschungsgemeinschaft (https://ror.org/018mejw64)
Alexander von Humboldt Foundation (https://ror.org/012kf4317)
Verband der Chemischen Industrie (https://ror.org/00kvk1853)
Depositing User: Felipe Fantuzzi
Date Deposited: 23 Dec 2023 01:07 UTC
Last Modified: 18 Dec 2024 00:00 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/104384 (The current URI for this page, for reference purposes)

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