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A systematic mid-infrared spectroscopic study of thermally processed SO2 ices

Mifsud, Duncan V., Herczku, Péter, Rahul, K. K., Ramachandran, Ragav, Sundararajan, Pavithraa, Kovács, Sándor T. S., Sulik, Béla, Juhász, Zoltán, Rácz, Richárd, Biri, Sándor, and others. (2023) A systematic mid-infrared spectroscopic study of thermally processed SO2 ices. Physical Chemistry Chemical Physics, 25 (38). pp. 26278-26288. ISSN 1463-9084. (doi:10.1039/d3cp03196a) (KAR id:102937)

Abstract

The use of mid-infrared spectroscopy to characterise the chemistry of icy interstellar and Solar System environments will be exploited in the near future to better understand the chemical processes and molecular inventories in various astronomical environments. This is, in part, due to observational work made possible by the recently launched James Webb Space Telescope as well as forthcoming missions to the outer Solar System that will observe in the mid-infrared spectroscopic region (e.g., the Jupiter Icy Moons Explorer and the Europa Clipper missions). However, such spectroscopic characterisations are crucially reliant upon the generation of laboratory data for comparative purposes. In this paper, we present an extensive mid-infrared characterisation of SO2 ice condensed at several cryogenic temperatures between 20 and 100 K and thermally annealed to sublimation in an ultrahigh-vacuum system. Our results are anticipated to be useful in confirming the detection (and possibly thermal history) of SO2 on various Solar System bodies, such as Ceres and the icy Galilean moons of Jupiter, as well as in interstellar icy grain mantles.

Item Type: Article
DOI/Identification number: 10.1039/d3cp03196a
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Funders: European Union (https://ror.org/019w4f821)
Royal Society (https://ror.org/03wnrjx87)
University of Kent (https://ror.org/00xkeyj56)
SWORD Depositor: JISC Publications Router
Depositing User: JISC Publications Router
Date Deposited: 26 Sep 2023 09:27 UTC
Last Modified: 11 Jan 2024 06:55 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/102937 (The current URI for this page, for reference purposes)

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