Tröster, Tobias, Endres, Franziska, Arrowsmith, Merle, Endres, Lukas, Fantuzzi, Felipe, Braunschweig, Holger (2023) Dibenzoberylloles: antiaromatic s-block fluorene analogues. Chemical Communications, 59 (60). pp. 9199-9202. ISSN 1359-7345. E-ISSN 1364-548X. (doi:10.1039/D3CC02736H) (KAR id:102067)
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| Official URL: https://doi.org/10.1039/D3CC02736H |
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Abstract
Among a series of Lewis-base-stabilised antiaromatic dibenzoberylloles (DBBes) the cyclic alkyl(amino)carbene (CAAC) analogue undergoes a complex but highly selective thermal decomposition, involving the breaking and making of four bonds each, which yields a rare beryllium η2-alkene complex. Two-electron reduction of the CAAC-stabilised DBBe analogue yields an aromatic dianion.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/D3CC02736H |
| Uncontrolled keywords: | Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis |
| Subjects: |
Q Science Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: |
Deutsche Forschungsgemeinschaft (https://ror.org/018mejw64)
Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) Alexander von Humboldt Foundation (https://ror.org/012kf4317) Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 12 Jul 2023 14:01 UTC |
| Last Modified: | 16 Apr 2024 14:05 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/102067 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
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