Koestler, Benedikt, Gilmer, Jannik, Bolte, Michael, Virovets, Alexander, Lerner, Hans‐Wolfram, Albert, Philipp, Fantuzzi, Felipe, Wagner, Matthias (2023) Group IV heteroadamantanes: synthesis of Si6Sn4 and site-selective derivatization of Si6Ge4. Chemical Communications, 59 (16). pp. 2295-2298. ISSN 1359-7345. E-ISSN 1364-548X. (doi:10.1039/D2CC06697A) (Access to this publication is currently restricted. You may be able to access a copy if URLs are provided) (KAR id:99828)
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Author's Accepted Manuscript
Language: English Restricted to Repository staff only until 30 January 2024. |
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![[thumbnail of Accepted_Manuscript.pdf]](https://kar.kent.ac.uk/style/images/fileicons/application_pdf.png) |
| Official URL: https://doi.org/10.1039/D2CC06697A |
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Abstract
The mixed heteroadamantanes Si6Ge4 and Si6Sn4 are readily accessible from Me2ECl2/Si2Cl6/cat. Cl– (4 × EMe2, 2 × SiCl2, 4 × Si–SiCl3 vertices; E = Ge, Sn). Different from Si6Ge4, two skeletal isomers are formed in the case of Si6Sn4. Site-selective SiCl3-methylation of Si6Ge4 was achieved, leaving the SiCl2 groups untouched.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/D2CC06697A |
| Uncontrolled keywords: | Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: | Evonik (Germany) (https://ror.org/01qmw3j63) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 31 Jan 2023 18:09 UTC |
| Last Modified: | 03 Mar 2023 16:17 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/99828 (The current URI for this page, for reference purposes) |
| Koestler, Benedikt: |  https://orcid.org/0000-0001-8208-5471 |
| Bolte, Michael: | https://orcid.org/0000-0001-5296-6251 |
| Virovets, Alexander: | https://orcid.org/0000-0002-8843-8503 |
| Lerner, Hans‐Wolfram: | https://orcid.org/0000-0003-1803-7947 |
| Fantuzzi, Felipe: | https://orcid.org/0000-0002-8200-8262 |
| Wagner, Matthias: | https://orcid.org/0000-0001-5806-8276 |
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