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Anomalous evolution of the magnetocaloric effect in dilute triangular Ising antiferromagnets Tb1xYx(HC O2)3

Falsaperna, Mario, Bulled, Johnathan M., Stenning, Gavin B. G., Goodwin, Andrew L., Saines, P.J. (2022) Anomalous evolution of the magnetocaloric effect in dilute triangular Ising antiferromagnets Tb1xYx(HC O2)3. Physical Review Materials, 6 (12). Article Number 124410. ISSN 2475-9953. (doi:10.1103/PhysRevMaterials.6.124410) (KAR id:98725)

Abstract

We investigate the effects of diamagnetic doping in the solid-solution series Tb1xYx(HC O2)3, in which the parent Tb(HC O2)3 phase has previously been shown to host a combination of frustrated and quasi-1D physics, giving rise to a triangular Ising antiferromagnetic ground state that lacks long range 3D order. Heat capacity measurements show three key features: (i) a low temperature Schottky anomaly is observed, which is constant as a function of x; (ii) the transition temperature and associated entropy change are both surprisingly robust to diamagnetic doping; and (iii) an additional contribution at T < 0.4 K appears with increasing x. The origin of this unusual behaviour is rationalised in terms of the fragmentation of quasi-1D spin chains by the diamagnetic Y3+ dopant. Magnetocaloric measurements show a nonlinear dependence on x. The mass-weighted magnetocaloric entropy decreases across the series from the promising values in (HC O2)3; however, the magnetocaloric entropy per magnetic Tb3+ ion first decreases then increases with increasing x. Our results establish Tb1xYx(HC O2)3 as a model system in which to explore the functional ramifications of dilution in a low dimensional magnet.

Item Type: Article
DOI/Identification number: 10.1103/PhysRevMaterials.6.124410
Additional information: For the purpose of open access, the author(s) has applied a Creative Commons Attribution (CC BY) licence to any Author Accepted Manuscript version arising.
Subjects: Q Science > QD Chemistry
Institutional Unit: Schools > School of Natural Sciences > Chemistry and Forensic Science
Former Institutional Unit:
Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders: Leverhulme Trust (https://ror.org/012mzw131)
Engineering and Physical Sciences Research Council (https://ror.org/0439y7842)
European Research Council (https://ror.org/0472cxd90)
Depositing User: Paul Saines
Date Deposited: 06 Dec 2022 10:14 UTC
Last Modified: 20 May 2025 10:01 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/98725 (The current URI for this page, for reference purposes)

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