Hagspiel, Stephan, Arrowsmith, Merle, Fantuzzi, Felipe, Vargas, Alfredo, Rempel, Anna, Hermann, Alexander, Brückner, Tobias, Braunschweig, Holger (2021) Intensiv farbige Bor-dotierte Thiazolthiazole durch reduktive Dimerisierung von Borisothiocyanaten. Angewandte Chemie, . ISSN 0044-8249. (doi:10.1002/ange.202015508) (KAR id:98614)
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Language: German 
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| Official URL: https://doi.org/10.1002/ange.202015508 |
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Abstract
Die Reduktion von (CAAC)BBr2(NCS) (CAAC=cyclisches Alkyl(amino)carben) in der Gegenwart einer Lewis-Base L liefert dreifach koordinierte (CAAC)LB(NCS)-Borylene, die eine reversible (E)/(Z)-Isomerisierung eingehen. Die gleiche Reduktion in Abwesenheit von L führt zu intensiv blauen, bis(CAAC)-stabilisierten, Bor-dotierten, aromatischen Thiazolthiazolen, die aus der Dimerisierung zweifach koordinierter (CAAC)B(NCS)-Borylenintermediate resultieren.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1002/ange.202015508 |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: |
Deutsche Forschungsgemeinschaft (https://ror.org/018mejw64)
Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) Alexander von Humboldt Foundation (https://ror.org/012kf4317) University of Sussex (https://ror.org/00ayhx656) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 01 Dec 2022 14:40 UTC |
| Last Modified: | 01 Dec 2022 14:40 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/98614 (The current URI for this page, for reference purposes) |
| Hagspiel, Stephan: |  https://orcid.org/0000-0002-6049-6007 |
| Arrowsmith, Merle: | https://orcid.org/0000-0003-1449-5932 |
| Fantuzzi, Felipe: | https://orcid.org/0000-0002-8200-8262 |
| Vargas, Alfredo: | https://orcid.org/0000-0001-7491-791X |
| Braunschweig, Holger: | https://orcid.org/0000-0001-9264-1726 |
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