Hermann, Alexander, Fantuzzi, Felipe, Arrowsmith, Merle, Zorn, Theresa, Krummenacher, Ivo, Ritschel, Benedikt, Radacki, Krzysztof, Engels, Bernd, Braunschweig, Holger (2020) Oxidation, Coordination, and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene. Angewandte Chemie International Edition, 59 (36). pp. 15717-15725. ISSN 1433-7851. (doi:10.1002/anie.202006131) (KAR id:98538)
|
PDF
Publisher pdf
Language: English 
This work is licensed under a Creative Commons Attribution 4.0 International License.
|
|
|
Download (5MB)
Preview
|
Preview |
|
This file may not be suitable for users of assistive technology.
Request an accessible format
|
|
|
PDF
Supplemental Material
Language: English |
|
|
Download (4MB)
Preview
|
Preview |
|
This file may not be suitable for users of assistive technology.
Request an accessible format
|
|
| Official URL: https://doi.org/10.1002/anie.202006131 |
|
Abstract
The reductive coupling of an N-heterocyclic carbene (NHC) stabilized (dibromo)vinylborane yields a 1,2-divinyldiborene, which, although isoelectronic to a 1,3,5-triene, displays no extended π conjugation because of twisting of the C2B2C2 chain. While this divinyldiborene coordinates to copper(I) and platinum(0) in an η2-B2 and η4-C2B2 fashion, respectively, it undergoes a complex rearrangement to an η4-1,3-diborete upon complexation with nickel(0).
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1002/anie.202006131 |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: |
European Research Council (https://ror.org/0472cxd90)
Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) Alexander von Humboldt Foundation (https://ror.org/012kf4317) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 30 Nov 2022 15:59 UTC |
| Last Modified: | 06 Dec 2022 14:48 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/98538 (The current URI for this page, for reference purposes) |
| Fantuzzi, Felipe: |  https://orcid.org/0000-0002-8200-8262 |
| Arrowsmith, Merle: | https://orcid.org/0000-0003-1449-5932 |
| Krummenacher, Ivo: | https://orcid.org/0000-0001-9537-1506 |
| Radacki, Krzysztof: | https://orcid.org/0000-0003-3088-6327 |
| Engels, Bernd: | https://orcid.org/0000-0003-3057-389X |
| Braunschweig, Holger: | https://orcid.org/0000-0001-9264-1726 |
- Link to SensusAccess
- Export to:
- RefWorks
- EPrints3 XML
- BibTeX
- CSV
- Depositors only (login required):
Altmetric
Altmetric
