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Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations

do Pim, Walace D., Silva, Ingrid F., da Silva Júnior, Eufrânio N., Stumpf, Humberto O., Oliveira, Willian X. C., Pedroso, Emerson F., Pinheiro, Carlos B., Journaux, Yves, Fantuzzi, Felipe, Krummenacher, Ivo, and others. (2021) Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations. Dalton Transactions, 50 . pp. 12430-12434. ISSN 1477-9226. (doi:10.1039/D1DT02268G) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:98530)

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https://doi.org/10.1039/D1DT02268G

Abstract

We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures.

Item Type: Article
DOI/Identification number: 10.1039/D1DT02268G
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders: National Council for Scientific and Technological Development (https://ror.org/03swz6y49)
Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614)
Alexander von Humboldt Foundation (https://ror.org/012kf4317)
Royal Society of Chemistry (https://ror.org/025sbr097)
Depositing User: Felipe Fantuzzi
Date Deposited: 30 Nov 2022 14:58 UTC
Last Modified: 06 Dec 2022 15:30 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/98530 (The current URI for this page, for reference purposes)

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