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Nees, Samuel, Fantuzzi, Felipe, Wellnitz, Tim, Fischer, Malte, Siewert, Jan-Erik, Goettel, James T., Hofmann, Alexander, Härterich, Marcel, Braunschweig, Holger, Hering-Junghans, Christian and others. (2021) Cyclo-Dipnictadialanes. Angewandte Chemie International Edition, 60 (45). pp. 24318-24325. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202111121) (KAR id:96282)

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Pnictaalenes with a pnictogen−aluminium double bond are inherently unstable and prone to dimerization. The synthesis of Lewis-base-free dipnictadialenes is revealed. It is shown that depending on the steric profile of the substituents either the alternating [CpxAl(μ-PAr)]2 dimers or the head-to-head species [ArPnAlCp3t]2 are formed. DFT studies corroborate that the different outcomes are thermodynamically driven.

Item Type: Article
DOI/Identification number: 10.1002/anie.202111121
Uncontrolled keywords: aluminium; carbene ligands; main group elements; phosphorus; small ring systems
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User: Felipe Fantuzzi
Date Deposited: 18 Aug 2022 08:18 UTC
Last Modified: 19 Aug 2022 08:30 UTC
Resource URI: (The current URI for this page, for reference purposes)
Fantuzzi, Felipe:
Fischer, Malte:
Goettel, James T.:
Härterich, Marcel:
Braunschweig, Holger:
Hering-Junghans, Christian:
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