Strain engineering of the magnetic anisotropy and moment in NdFeO3 epitaxial thinfilms

Strain engineering is a powerful mean for tuning the various functionalities of ABO3 perovskite oxide thin films. Rare-earth orthoferrite RFeO3 materials such as NdFeO3 (NFO) are of prime interest because of their intriguing magnetic properties as well as their technological potential applications especially as thin films. Here, using a large set of complementary and advanced techniques, we show that NFO epitaxial thin films, successfully grown by pulsed laser deposition on (001)-SrTiO3, show a strong magnetic anisotropy below a critical thickness tc of ~54 nm, associated to the occurrence of structural modifications related to symmetry and domain pattern changes. By varying the tensile misfit strain through the decrease of film thickness below tc, the amplitudes of in- and out-of-plane magnetization can be continuously tuned while their ratio keeps constant. Furthermore, different low temperature magnetic behaviours are evidenced for strained and relaxed films suggesting that the strain-induced structural state impacts the magnetic phase stability.