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A Short, Versatile Route Towards Benzothiadiazinyl Radicals

Clark, Ewan R, Saines, Paul J. (2021) A Short, Versatile Route Towards Benzothiadiazinyl Radicals. Chemical Science, . ISSN 2041-6520. (doi:10.1039/D1SC04248C) (KAR id:91710)

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Abstract

A family of substituted 1,2,4-benzothiadiazine 1-chlorides have been prepared by treatment of N-arylamidines in neat

thionyl chloride at reflux. The S(IV) 1-chlorides are readily reduced under mild conditions to persistent 1,2,4-

benzothiadiazinyl radicals which have been characterised by EPR spectroscopy and cyclic voltammetry. Crystallographic

studies on isolated radicals indicate that the radicals dimerise via pancake bonding in the solid-state, resulting in

spin-pairing and net diamagnetism.

Item Type: Article
DOI/Identification number: 10.1039/D1SC04248C
Subjects: Q Science > QD Chemistry > QD156 Inorganic synthesis
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User: Ewan Clark
Date Deposited: 24 Nov 2021 09:28 UTC
Last Modified: 09 Dec 2021 08:53 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/91710 (The current URI for this page, for reference purposes)
Clark, Ewan R: https://orcid.org/0000-0001-7287-2631
Saines, Paul J.: https://orcid.org/0000-0002-4207-2112
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