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Ambient Temperature Synthesis and Structural Characterisation of Six Transition Metal Acetylenedicarboxylate Coordination Polymers

Best-Thompson, Luke, Saines, Paul J. (2020) Ambient Temperature Synthesis and Structural Characterisation of Six Transition Metal Acetylenedicarboxylate Coordination Polymers. Zeitschrift fur Anorganische und Allgemeine Chemie, 646 (19). pp. 1618-1625. ISSN 0044-2313. (doi:10.1002/zaac.202000265) (KAR id:82864)

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Abstract

This work reports the ambient temperature synthesis and structural characterisation of six new first row transition metal acetylenedicarboxylate coordination polymers. The Co and two Ni compounds adopt structures in which the octahedral metals are connected into 1D chains via the acetylenedicarboxylate ligand. In contrast the Mn and two Zn compounds adopt 3D metal-organic frameworks; while the Mn compound is non-porous the two Zn structures contain dimeric or trimeric clusters connected into frameworks that are potentially porous. These two anionic metal-organic frameworks are, however, charged balanced by cations siting in their pores which greatly reduces the ability to access their porosity.

Item Type: Article
DOI/Identification number: 10.1002/zaac.202000265
Subjects: Q Science
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: Paul Saines
Date Deposited: 11 Sep 2020 09:14 UTC
Last Modified: 15 Oct 2020 14:24 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/82864 (The current URI for this page, for reference purposes)
Saines, Paul J.: https://orcid.org/0000-0002-4207-2112
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