Ng, Kendrick K. L., Devlia, Reema, Foss, Nicola, Alesbrook, L.S., Hiscock, Jennifer R., Murray, Alexander T. (2020) Ionicity-dependent proton-coupled electron transfer of supramolecular self-assembled electroactive heterocycles. Chemical Communications, . ISSN 1359-7345. (doi:10.1039/D0CC05017B) (KAR id:82835)
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Official URL: https://doi.org/10.1039/D0CC05017B |
Abstract
Herein, we investigate the electrochemical properties of a class of Supramolecular Self-associated Amphiphilic salts (SSAs). We show that varying ionic strength of an SSA solution can cause a switching of the thermodynamics and kinetics of electron transfer. The effect of self-assembly on proton-coupled electron transfer has implications for the understanding of electron transfer kinetics in aqueous organic redox flow batteries, especially at high concentration where organic–organic intermolecular interactions become dominant even for highly soluble organic species.
Item Type: | Article |
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DOI/Identification number: | 10.1039/D0CC05017B |
Subjects: |
Q Science Q Science > Q Science (General) Q Science > QD Chemistry |
Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
Depositing User: | Jennifer Hiscock |
Date Deposited: | 09 Sep 2020 13:56 UTC |
Last Modified: | 21 Oct 2022 14:12 UTC |
Resource URI: | https://kar.kent.ac.uk/id/eprint/82835 (The current URI for this page, for reference purposes) |
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