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Sequence Isomerism in Uniform Polyphosphoesters Programmes Self-Assembly and Folding

Appukutti, Nadeema, Serpell, Christopher J., Jones, Joseph R. (2020) Sequence Isomerism in Uniform Polyphosphoesters Programmes Self-Assembly and Folding. Chemical Communications, (56). pp. 5307-5310. ISSN 1359-7345. (doi:10.1039/D0CC01319F) (KAR id:78376)

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https://doi.org/10.1039/D0CC01319F

Abstract

We have adapted solid phase phosphoramidite synthesis commonly used to make DNA, to produce two sequence-isomeric non-biological polymers which display sequence-programmed folding and self-assembly, going beyond structures which would be trivially anticipated. These findings open up possibilities for more sophisticated sequence/structure relationships using the same synthetic platform.

Item Type: Article
DOI/Identification number: 10.1039/D0CC01319F
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: Christopher Serpell
Date Deposited: 07 Nov 2019 14:28 UTC
Last Modified: 28 May 2020 08:31 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/78376 (The current URI for this page, for reference purposes)
Appukutti, Nadeema: https://orcid.org/0000-0002-6848-2128
Serpell, Christopher J.: https://orcid.org/0000-0002-2848-9077
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