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Multiple rare-earth ion environments in amorphous (Gd2O3)0.230(P2O5)0.770 revealed by gadolinium K-edge anomalous x-ray scattering

Cole, Jacqueline M., Cramer, Alisha J., Shastri, Sarvjit D., Mukaddem, Karim T., Newport, Robert J. (2018) Multiple rare-earth ion environments in amorphous (Gd2O3)0.230(P2O5)0.770 revealed by gadolinium K-edge anomalous x-ray scattering. Physical Review Materials, 2 (4). 045604. ISSN 2475-9953. (doi:10.1103/PhysRevMaterials.2.045604) (KAR id:73487)

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Abstract

A Gd

-edge anomalous x-ray scattering (AXS) study is performed on the rare-earth

R

phosphate glass,

G

2

3

0.230

P

O

)

, in order to determine

separations in its local structure. The minimum rare-earth separation is of particular interest given that the optical properties of these glasses can quench when rare-earth ions become too close to each other. To this end, a weak

pairwise correlation is located at

(

)

, which is representative of a metaphosphate

separation. More intense first-neighbor

pairwise correlations are found at the larger radial distributions, 4.8(1), 5.1(1), and

(

)

. These reflect a mixed ultraphosphate and metaphosphate structural character, respectively. A second-neighbor

pairwise correlation lies at

(

)

which is indicative of metaphosphate structures. Meta- and ultraphosphate classifications are made by comparing the

separations against those of rare-earth phosphate crystal structures,

(

O

)

and

P

O

, respectively, or difference pair-distribution function

Δ

)

Gd

Gd

Δ

that represent the AXS signal. Indeed, the spatial resolution is so good that it also enables the identification of

(

=

, P, O) pairwise correlations up to

Å

r

7.1

1

, 7.6(1), 7.9(1), 8.4(1), and

(

)

. This is a report of a Gd

-edge AXS study on an amorphous material. Its demonstrated ability to characterize the local structure of a glass up to such a long range of

heralds exciting prospects for AXS studies on other ternary noncrystalline materials. However, the technical challenge of such an experiment should not be underestimated, as is highlighted in this work where probing AXS signal near the Gd

edge is found to produce inelastic x-ray scattering that precludes the normal AXS methods of data processing. Nonetheless, it is shown that AXS results are not only tractable but they also reveal local structure of rare-earth phosphate glasses that is important from a materials-centered perspective and which could not be obtained by other materials characterization methods.

Item Type: Article
DOI/Identification number: 10.1103/PhysRevMaterials.2.045604
Uncontrolled keywords: Chemical bonding, Optical & microwave phenomena, Structural properties, Amorphous materials, X-ray absorption spectroscopy, X-ray diffraction, X-ray pair-distribution function analysis, X-ray techniques
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: Robert Newport
Date Deposited: 15 Apr 2019 11:10 UTC
Last Modified: 03 Jun 2019 09:41 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/73487 (The current URI for this page, for reference purposes)
Newport, Robert J.: https://orcid.org/0000-0002-2365-992X
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