Skip to main content

Emergent Magnetic Order and Correlated Disorder in Formate Metal-organic Frameworks

Dixey, R.J.C, Orlandi, Fabio, Manuel, P, Mukherjee, P, Dutton, S.E, Saines, Paul J. (2019) Emergent Magnetic Order and Correlated Disorder in Formate Metal-organic Frameworks. Philosophical Transactions of the Royal Society A, 337 (2149). ISSN 0264-3820. (doi:10.1098/rsta.2019.0007) (KAR id:73382)

PDF Author's Accepted Manuscript
Language: English
Download (1MB) Preview
Official URL


Magnetic materials with strong local interactions

a curiosity of physicists. Probing their magnetic

properties they can exhibit. Metal-organic frameworks

can produce more exotic structures, allowing for

in conventional metal-oxide materials. Historically,

been overlooked but has attracted greater attention

we investigate the magnetic structure of metal-organic

susceptibility and neutron diffraction. In Tb(DCO2)3

below 1.2 K, consisting of two k-vectors. Ho(DCO2)3

with ferromagnetic chains packed in a frustrated

Tb(DCO2)3 above 1.2 K. The other lanthanides show

suggest an Ising-like 1D magnetic order associated

properties, of some members in this family, improving

at higher temperatures.

Item Type: Article
DOI/Identification number: 10.1098/rsta.2019.0007
Uncontrolled keywords: magnetocaloric, correlated disorder, metal-organic framework, emergent order
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: Paul Saines
Date Deposited: 05 Apr 2019 08:17 UTC
Last Modified: 17 Jun 2019 08:34 UTC
Resource URI: (The current URI for this page, for reference purposes)
Saines, Paul J.:
  • Depositors only (login required):