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Electrochemical Evaluation of Pb, Ag, and Zn Cyanamides/Carbodiimides

Arayamparambil, Jeethu Jiju, Mann, Markus, Liu, Xiaohui, Alfredsson, Maria, Dronskowski, Richard, Stievano, Lorenzo, Sougrati, Moulay Tahar (2019) Electrochemical Evaluation of Pb, Ag, and Zn Cyanamides/Carbodiimides. ACS Omega, 4 (2). pp. 4339-4347. ISSN 2470-1343. (doi:10.1021/acsomega.8b02748) (KAR id:73272)

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PbNCN, Ag2NCN, and ZnNCN were tested as negative

electrochemical mechanism by X-ray diffraction and X-ray absorption

compounds react with lithium via a two-step reaction, starting with

irreversible for the three compounds, whereas the reversibility of the alloying

Ag2NCN which contain the cyanamide group (NC−N2−) and more

of the more covalent, cyanamide-type PbNCN and Ag2NCN, the conversion

carbodiimide-type ZnNCN, correlated with the nature of bonding in the

performance, with no improvement in capacity as it would have been expected from the combination of conversion and


Item Type: Article
DOI/Identification number: 10.1021/acsomega.8b02748
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: Maria Alfredsson
Date Deposited: 29 Mar 2019 10:24 UTC
Last Modified: 06 May 2020 03:19 UTC
Resource URI: (The current URI for this page, for reference purposes)
Alfredsson, Maria:
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