Gale, Philip A., Hiscock, Jennifer R., Jie, C. Z., Hursthouse, Michael B., Light, Mark E. (2010) Acyclic indole and carbazole-based sulfate receptors. Chemical Science, 7 (9). pp. 215-220. ISSN 2041-6520. (doi:10.1039/C0SC00202J) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication) | |
| Official URL http://dx.doi.org/10.1039/C0SC00202J |
Abstract
The anion complexation properties of a series of acyclic receptors consisting of diindolylurea groups appended with amide, amidoindole or amidocarbazole groups have been studied. The receptors selectively bind and encapsulate sulfate via either six or eight hydrogen bonds. Receptors containing eight hydrogen bond donors perturb the pKa of bound dihydrogen phosphate and bicarbonate to the extent that they are deprotonated by free anion in solution.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/C0SC00202J |
| Subjects: | Q Science > QD Chemistry |
| Divisions: |
Faculties > Sciences > School of Physical Sciences Faculties > Sciences > School of Physical Sciences > Functional Materials Group |
| Depositing User: | Jennifer Hiscock |
| Date Deposited: | 07 Dec 2018 16:12 UTC |
| Last Modified: | 23 Jan 2020 04:15 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/70819 (The current URI for this page, for reference purposes) |
| Hiscock, Jennifer R.: |  https://orcid.org/0000-0002-1406-8802 |
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