Gale, Philip A., Hiscock, Jennifer R., Jie, C. Z., Hursthouse, Michael B., Light, Mark E. (2010) Acyclic indole and carbazole-based sulfate receptors. Chemical Science, 7 (9). pp. 215-220. ISSN 2041-6520. (doi:10.1039/C0SC00202J) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:70819)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication) | |
| Official URL http://dx.doi.org/10.1039/C0SC00202J |
Abstract
The anion complexation properties of a series of acyclic receptors consisting of diindolylurea groups appended with amide, amidoindole or amidocarbazole groups have been studied. The receptors selectively bind and encapsulate sulfate via either six or eight hydrogen bonds. Receptors containing eight hydrogen bond donors perturb the pKa of bound dihydrogen phosphate and bicarbonate to the extent that they are deprotonated by free anion in solution.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/C0SC00202J |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > School of Physical Sciences |
| Depositing User: | Jennifer Hiscock |
| Date Deposited: | 07 Dec 2018 16:12 UTC |
| Last Modified: | 16 Feb 2021 14:00 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/70819 (The current URI for this page, for reference purposes) |
| Hiscock, Jennifer R.: |  https://orcid.org/0000-0002-1406-8802 |
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