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Acyclic indole and carbazole-based sulfate receptors

Gale, Philip A., Hiscock, Jennifer R., Jie, C. Z., Hursthouse, Michael B., Light, Mark E. (2010) Acyclic indole and carbazole-based sulfate receptors. Chemical Science, 7 (9). pp. 215-220. ISSN 2041-6520. (doi:10.1039/C0SC00202J) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1039/C0SC00202J

Abstract

The anion complexation properties of a series of acyclic receptors consisting of diindolylurea groups appended with amide, amidoindole or amidocarbazole groups have been studied. The receptors selectively bind and encapsulate sulfate via either six or eight hydrogen bonds. Receptors containing eight hydrogen bond donors perturb the pKa of bound dihydrogen phosphate and bicarbonate to the extent that they are deprotonated by free anion in solution.

Item Type: Article
DOI/Identification number: 10.1039/C0SC00202J
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences
Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Jennifer Hiscock
Date Deposited: 07 Dec 2018 16:12 UTC
Last Modified: 23 Jan 2020 04:15 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/70819 (The current URI for this page, for reference purposes)
Hiscock, Jennifer R.: https://orcid.org/0000-0002-1406-8802
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