2-Amidoindole-based anion receptors

Caltagirone, Claudia, Gale, Philip A., Hiscock, Jennifer R., Hursthouse, Michael B., Light, Mark E., Gale, Philip A., Tizzard, Graham J. (2009) 2-Amidoindole-based anion receptors. Supramolecular Chemistry, 21 (1-2). pp. 125-130. ISSN 1061-0278. (doi:10.1080/10610270802348243) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:70814)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: https://doi.org/10.1080/10610270802348243

Abstract

Four receptors containing either 2-amidoindole or 7-nitro-2-amidoindole groups have been synthesised and shown to complex oxoanions in DMSO-d 6/0.5% water solution. X-ray crystal structure elucidation reveals that receptor 1 complexes dihydrogen phosphate ion pairs in the solid state, which are part of a continuous chain. While this receptor binds dihydrogen phosphate in a 1:1 stoichiometry in solution, compound 4, which contains 7-nitroindole groups, does form 1:2 receptor:dihydrogen phosphate complexes in DMSO-d 6/0.5% water.

Item Type:	Article
DOI/Identification number:	10.1080/10610270802348243
Uncontrolled keywords:	anion binding, indole, hydrogen bonding, crystallography
Subjects:	Q Science > QD Chemistry
Divisions:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Jennifer Hiscock
Date Deposited:	07 Dec 2018 15:50 UTC
Last Modified:	16 Nov 2021 10:25 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/70814 (The current URI for this page, for reference purposes)

University of Kent Author Information

Hiscock, Jennifer R..

Creator's ORCID:	https://orcid.org/0000-0002-1406-8802
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