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Evidence of a cubic iron sub-lattice in t-CuFe2O4 demonstrated by X-ray Absorption Fine Structure

Caddeo, Francesco, Loche, Danilo, Casula, Maria F., Corrias, Anna (2018) Evidence of a cubic iron sub-lattice in t-CuFe2O4 demonstrated by X-ray Absorption Fine Structure. Scientific Reports, 8 (797). ISSN 2045-2322. (doi:10.1038/s41598-017-19045-8) (KAR id:65699)

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Abstract

Copper ferrite, belonging to the wide and technologically relevant class of spinel ferrites, was grown in the form of t-CuFe2O4 nanocrystals within a porous matrix of silica in the form of either an aerogel or a xerogel, and com-pared to a bulk sample. Extended X-ray absorption fine structure (EXAFS) spectroscopy revealed the presence of two different sub-lattices within the crystal structure of t-CuFe2O4, one tetragonal and one cubic, defined by the Cu2+ and Fe3+ ions respectively. Our investigation provides evidence that the Jahn-Teller distortion, which occurs on the Cu2+ ions located in octahedral sites, does not affect the coordination geometry of the Fe3+ ions, regardless of their location in octahedral or tetrahedral sites.

Item Type: Article
DOI/Identification number: 10.1038/s41598-017-19045-8
Subjects: Q Science
Divisions: Divisions > Division of Natural Sciences > School of Physical Sciences
Depositing User: Anna Corrias
Date Deposited: 10 Jan 2018 11:43 UTC
Last Modified: 16 Feb 2021 13:52 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/65699 (The current URI for this page, for reference purposes)
Corrias, Anna: https://orcid.org/0000-0002-5190-8196
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