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The first entry to 5,6-dihydroxy-3-mercaptoindole, 5-hydroxy-3-mercaptoindole and their 2-carbomethoxy derivatives by a mild thiocyanation/reduction methodology

Pezzella, Alessandro, Palma, Aniello, Iadonisi, Alfonso, Napolitano, Alessandra, d’Ischia, Marco (2007) The first entry to 5,6-dihydroxy-3-mercaptoindole, 5-hydroxy-3-mercaptoindole and their 2-carbomethoxy derivatives by a mild thiocyanation/reduction methodology. Tetrahedron Letters, 48 (22). pp. 3883-3886. ISSN 0040-4039. (doi:10.1016/j.tetlet.2007.03.141) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:64620)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL
https://doi.org/10.1016/j.tetlet.2007.03.141

Abstract

The hitherto unknown 5,6-dihydroxy-3-mercaptoindole (4a) and its 2-carbomethoxy derivative (4b), as well as the analogous 5-hydroxy 3-mercaptoindoles, have been conveniently obtained as O,S-acetyl derivatives 3a–d by thiocyanation of the corresponding acetoxyindoles 1a–d with the NH4SCN/oxone system followed by SmI2 reduction and acetylation.

Item Type: Article
DOI/Identification number: 10.1016/j.tetlet.2007.03.141
Subjects: Q Science
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User: Aniello Palma
Date Deposited: 22 Nov 2017 11:41 UTC
Last Modified: 16 Nov 2021 10:24 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/64620 (The current URI for this page, for reference purposes)
Palma, Aniello: https://orcid.org/0000-0001-9626-4390
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