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Synthesis of poly ? ketoesters via double acylketene trapping

Palma, Aniello, Serginson, James M., Barrett, Anthony G.M. (2014) Synthesis of poly ? ketoesters via double acylketene trapping. Tetrahedron Letters, 56 (5). pp. 674-676. ISSN 0040-4039. (doi:10.1016/j.tetlet.2014.12.036) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
https://doi.org/10.1016/j.tetlet.2014.12.036

Abstract

The synthesis and characterization of polymeric ? ketoesters is herein reported. These polymers were prepared by allowing highly electrophilic acylketenes, generated in situ via thermolysis of stable 6-substituted-2,2-dimethyl-4H-1,3-dioxin-4-ones, to react with diol co-monomers. A relationship between polymer molecular weights and reaction conditions was established.

Item Type: Article
DOI/Identification number: 10.1016/j.tetlet.2014.12.036
Subjects: Q Science > QD Chemistry > QD431 Organic Chemistry- Biochemistry- Proteins, peptides, amino acids
Divisions: Faculties > Sciences > School of Physical Sciences
Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Aniello Palma
Date Deposited: 22 Nov 2017 11:24 UTC
Last Modified: 01 Aug 2019 10:42 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/64612 (The current URI for this page, for reference purposes)
Palma, Aniello: https://orcid.org/0000-0001-9626-4390
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