Coupling and electrical control of structural, orbital and magnetic orders in perovskites

Varignon, Julien, Bristowe, Nicholas C., Bousquet, Eric, Ghosez, Philippe (2015) Coupling and electrical control of structural, orbital and magnetic orders in perovskites. Scientific Reports, 5 . ISSN 2045-2322. (doi:10.1038/srep15364)

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Abstract

Perovskite oxides are already widely used in industry and have huge potential for novel device applications thanks to the rich physical behaviour displayed in these materials. The key to the functional electronic properties exhibited by perovskites is often the so-called Jahn-Teller distortion. For applications, an electrical control of the Jahn-Teller distortions, which is so far out of reach, would therefore be highly desirable. Based on universal symmetry arguments, we determine new lattice mode couplings that can provide exactly this paradigm, and exemplify the effect from first-principles calculations. The proposed mechanism is completely general, however for illustrative purposes, we demonstrate the concept on vanadium based perovskites where we reveal an unprecedented orbital ordering and Jahn-Teller induced ferroelectricity. Thanks to the intimate coupling between Jahn-Teller distortions and electronic degrees of freedom, the electric field control of Jahn-Teller distortions is of general relevance and may find broad interest in various functional devices.

Item Type: Article
DOI/Identification number: 10.1038/srep15364
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QC Physics > QC176 Solid state physics
Q Science > QD Chemistry > QD478 Solid State Chemistry
Q Science > QC Physics > QC176.8.N35 Nanoscience, nanotechnology
Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Divisions: Faculties > Sciences > School of Physical Sciences
Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Nicholas Bristowe
Date Deposited: 21 Feb 2017 16:54 UTC
Last Modified: 29 May 2019 18:38 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/60251 (The current URI for this page, for reference purposes)
Bristowe, Nicholas C.: https://orcid.org/0000-0003-1286-8440
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