Three-body interactions and the phase equilibria of mixtures

Marcelli, Gianluca and Sadus, Richard J (2001) Three-body interactions and the phase equilibria of mixtures. HIGH TEMPERATURES HIGH PRESSURES, 33 (1). pp. 111-118. ISSN 0018-1544. (doi:https://doi.org/10.1068/htwu244) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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http://dx.doi.org/10.1068/htwu244

Abstract

Gibbs ensemble Monte-Carlo simulations are reported for the vapour-liquid phase coexistence of the binary argon - krypton mixture. The calculations employ accurate two-body potentials in addition to contributions from three-body dispersion resulting from third-order triple-dipole interactions. The calculations are in good overall agreement with experiment. The composition of coexisting vapour and liquid phases is relatively unaffected by three-body interactions. In contrast, three-body interactions affect substantially the density of the liquid phase.

Item Type: Article
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Divisions: Faculties > Sciences > School of Engineering and Digital Arts
Faculties > Sciences > School of Engineering and Digital Arts > Instrumentation, Control and Embedded Systems
Depositing User: Gianluca Marcelli
Date Deposited: 11 Nov 2015 16:18 UTC
Last Modified: 12 Nov 2015 11:08 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/51568 (The current URI for this page, for reference purposes)
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