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Synthesis, reactivity, structure and electronic properties of [N(CH3)4]C60·1.5thf: Fullerides with simple hexagonal packing

Douthwaite, R.E., Green, M.A., Green, M.L.H., Rosseinsky, M.J. (1996) Synthesis, reactivity, structure and electronic properties of [N(CH3)4]C60·1.5thf: Fullerides with simple hexagonal packing. Journal of Materials Chemistry, 6 (12). pp. 1913-1920. ISSN 0959-9428. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:51161)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
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Abstract

The preparation of [N(CH3)4] C60 ·1.5thf and characterisation of its electronic properties, using susceptibility, EPR and 13C MAS NMR measurements, is reported. X-Ray powder diffraction shows a simple hexagonal stacking sequence of close-packed C60 layers, with cations and solvent molecules located in the trigonal-prismatic sites. The electronic properties are consistent with narrow-band metallic behaviour at high temperature. A transition in susceptibility and EPR measurements is seen between 200 and 230 K. A similar synthesis affords a C60 2- compound with the same simple hexagonal fulleride packing.

Item Type: Article
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - J. Mater. Chem. [Field not mapped to EPrints] AD - Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User: Giles Tarver
Date Deposited: 21 Oct 2015 11:30 UTC
Last Modified: 16 Nov 2021 10:21 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/51161 (The current URI for this page, for reference purposes)

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