A gadolinium diphenate coordination polymer, â?? 1[Gd2(H2O)2(C14H 8O4)3], with one-dimensional structure

Thirumurugan, A. and Pati, S.K. and Green, M.A. and Natarajan, S. (2004) A gadolinium diphenate coordination polymer, â?? 1[Gd2(H2O)2(C14H 8O4)3], with one-dimensional structure. Zeitschrift fur Anorganische und Allgemeine Chemie, 630 (4). pp. 579-584. ISSN 0044-2313. (doi:http://dx.doi.org/) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

A hydrothermal reaction of Gd(NO3)3 and 2,2â?²-diphenic acid give rise to a new coordination compound â?? 1[Gd2(H2O) 2-(C14H8O4)3] with one-dimensional structure. Single crystal X-ray studies shows that the compound has infinite O-Gd-O one-dimensional chains resulting from a bonding between Gd3+ cations and diphenate anions. The Gd3+ ions are distorted dodecahedra with respect to oxygen atoms. Magnetic investigations show no ordering up to 4K and the compound exhibit photoluminescence at room temperature.

Item Type: Article
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Z. Anorg. Allg. Chem. [Field not mapped to EPrints] AD - Chem. and Physics of Materials Unit, Jawaharlal Nehru Ctr. Adv. Sci. Res., Bangalore, India [Field not mapped to EPrints] AD - Theoretical Sciences Unit, Jawaharlal Nehru Ctr. Adv. Sci. Res., Bangalore, India [Field not mapped to EPrints] AD - Davy-Faraday Research Laboratory, Royal Institution of Great Britain, London, United Kingdom [Field not mapped to EPrints] AD - Framework Solids Laboratory, Chem. and Physics of Materials Unit, Jawaharlal Nehru Ctr. Adv. Sci. Res., Jakkur P.O., Bangalore 560 064, India [Field not mapped to EPrints] AD - Theoretical Sciences Unit, Jawaharlal Nehru Ctr. Adv. Sci. Res., Jakkur P.O., Bangalore 560 064, India [Field not mapped to EPrints] AD - Davy-Faraday Research Laboratory, Royal Institution of Great Britain, 21 Albemarle Street, London W1S 4BS, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Diphenic acid, Gadolinium, Hydrothermal synthesis, gadolinium, polymer, article, atomic particle, chemical bond, chemical reaction, chemical structure, crystal structure, hydrothermal vent, photoluminescence, room temperature, X ray analysis
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 21 Oct 2015 15:14 UTC
Last Modified: 23 Oct 2015 11:11 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/51125 (The current URI for this page, for reference purposes)
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