Skip to main content

Synthesis, structure and magnetic properties of a new one-dimensional iron phosphite, [FeIII(1,10-phenanthroline)(HPO3)(H 2PO3)]

Mandal, S., Green, M.A., Natarajan, S. (2005) Synthesis, structure and magnetic properties of a new one-dimensional iron phosphite, [FeIII(1,10-phenanthroline)(HPO3)(H 2PO3)]. Current Science, 89 (11). pp. 1899-1903. ISSN 0011-3891. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://www.scopus.com/inward/record.url?eid=2-s2.0...

Abstract

A new iron phosphite, [FeIII(1,10-phen)(HPO3)(H 2PO3)], I, has been synthesized hydrothermally from a mixture containing iron powder, phosphorous acid, 1,10-phenanthroline and water at 125°C for 7 days. The structure consists of an edge-shared four-membered rings formed by the connectivity between FeO4N2 octahedra and pseudo pyramidal HPO3 units, connected through their edges forming a one-dimensional structure. The 1,10-phenanthroline molecules and H2PO3 pseudo-tetrahedral units bound with the Fe centre project into the inter-chain spaces. Magnetic investigations reveal that the iron is present in +3 oxidation state, and at low-temperature the sample orders antiferromagnetically with TN = â?¼ 16 K. Crystal data: I, monoclinic, space group = P2(1)/m (no. 11), a = 10.180(3), b = 6.424(1), c = 11.6668(5) Ã?, β = 115.59(1)° , V = 668.2(4) Ã?3, Z = 4, Ï?calc = 1.880 g/cm3, μ (Mo Kα) = 3.456 mm-1, R1 = 0.0313 and wR2 = 0.0725 data [I < 2Ï?(I)].

Item Type: Article
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Curr. Sci. [Field not mapped to EPrints] AD - Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India [Field not mapped to EPrints] AD - Davy-Faraday Research Laboratory, Royal Institution of Great Britain, 21 Albermarle Street, London WIS 4BS, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Ï?...Ï? interaction, Antiferromagnetic interactions, Iron-phosphite, Single crystal structure, Synthesis
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 21 Oct 2015 15:26 UTC
Last Modified: 29 May 2019 16:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/51115 (The current URI for this page, for reference purposes)
  • Depositors only (login required):