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Open metal sites within isostructural metal-organic frameworks for differential recognition of acetylene and extraordinarily high acetylene storage capacity at room temperature

Xiang, S., Zhou, W., Zhang, Z., Green, M.A., Liu, Y., Chen, B. (2010) Open metal sites within isostructural metal-organic frameworks for differential recognition of acetylene and extraordinarily high acetylene storage capacity at room temperature. Angewandte Chemie - International Edition, 49 (27). pp. 4615-4618. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.201000094) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1002/anie.201000094

Abstract

Chemical equcation Presented On the metal: Open metal sites within isostructural [M2(DHTP)] metal-organic frameworks (M = Co 2-, Mn2+, Mg2+, and Zn2+; DHTP = 2,5-dihydroxyterephthalate) exhibit differential molecular recognition with acetylene. The extremely strong interaction of Co2+with acetylene (see structure) makes [Co2(DHTP)] the highest volumetric acetylene storage material with a capacity of 230 cm3cm-3 at 295 K and 1 atm. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type: Article
DOI/Identification number: 10.1002/anie.201000094
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Angew. Chem. Int. Ed. [Field not mapped to EPrints] C2 - 20491101 [Field not mapped to EPrints] AD - Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698, United States [Field not mapped to EPrints] AD - NIST Center for Neutron Research, Caithersburg, MD 20899-6100, United States [Field not mapped to EPrints] AD - Department of Chemical Engineering, University of Delaware, Newark, DE 19716, United States [Field not mapped to EPrints] AD - Department of Materials Science and Engineering, University of Maryland, College Park, MD 20742, United States [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Acetylene, Mesoporous materials, Metal-organic frameworks, Molecular recognition, Structure elucidation, Isostructural, Metal organic framework, Metal sites, Metal-organic frameworks, Room temperature, Storage capacity, Strong interaction, Structure elucidation, Acetylene, Lighting, Manganese, Manganese compounds, Mesoporous materials, Molecular biology, Molecular recognition, Zinc, Metals, acetylene, metal, phthalic acid derivative, article, chemical structure, chemistry, conformation, temperature, X ray crystallography, Acetylene, Crystallography, X-Ray, Metals, Models, Molecular, Molecular Conformation, Phthalic Acids, Temperature
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 15 Oct 2015 11:20 UTC
Last Modified: 29 May 2019 16:09 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/51001 (The current URI for this page, for reference purposes)
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