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The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes

Dillon, K.B., Goeta, A.E., Monks, P.K., Shepherd, H.J. (2010) The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes. Polyhedron, 29 (1). pp. 606-612. ISSN 0277-5387. (doi:10.1016/j.poly.2009.07.040) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Official URL
http://dx.doi.org/10.1016/j.poly.2009.07.040

Abstract

The molecular structure of the 2-aryl-1,3,2-dioxaphospholane, 2,6-(CF 3) 2-C 6H 3-P(OCH 2) 2 (1), has been determined by single-crystal X-ray diffraction at 120 K. Its reactions with the platinum(II) dimers trans-[PtCl(μ-Cl)(PEt 3)] 2, trans-[PtCl(μ-Cl)(PPh 2Me)] 2, trans-[PtCl(μ-Cl)(PPhMe 2)] 2 and trans-[PtBr(μ-Br)(PEt 3)] 2 have been investigated using 31P NMR solution-state spectroscopy. Monomeric trans- and cis-Pt(II) complexes were formed; the molecular structures of cis-[PtCl 2(L)(PR 2R�)] (R{double bond, long}R�{double bond, long}Et (3), R{double bond, long}Ph, R�{double bond, long}Me (7)), cis-[PtBr 2L(PEt 3)] (9) and cis-[PtCl 2L 2] (10), where L = 2,6-(CF 3) 2-C 6H 3-P(OCH 2) 2, have been ascertained at 120 K. © 2009 Elsevier Ltd. All rights reserved.

Item Type: Article
DOI/Identification number: 10.1016/j.poly.2009.07.040
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Polyhedron [Field not mapped to EPrints] AD - Chemistry Department, Durham University, South Road, Durham, DH1 3LE, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Molecular structures, Phospholane, Phosphonite, Phosphorus NMR, Platinum(II) complexes
Subjects: Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 15 Oct 2015 13:02 UTC
Last Modified: 29 May 2019 16:06 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/50841 (The current URI for this page, for reference purposes)
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