Skip to main content

The effect of an active guest on the spin crossover phenomenon

Bao, X., Shepherd, H.J., Salmon, L., Molnár, G., Tong, M.-L., Bousseksou, A. (2013) The effect of an active guest on the spin crossover phenomenon. Angewandte Chemie - International Edition, 52 (4). pp. 1198-1202. ISSN 14337851 (ISSN). E-ISSN 1521-3773. (doi:10.1002/anie.201207218) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
https://doi.org/10.1002/anie.201207218

Abstract

Throw the switch: A new strategy for regulating spin crossover (SCO) properties by the control of an active guest molecule is proposed. As a proof of concept, maleic anhydride was incorporated into a microporous {Fe(pyrazine)[Pt(CN)4]} framework material and chemically switched to maleic acid, thus modifying the SCO properties (see picture). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type: Article
DOI/Identification number: 10.1002/anie.201207218
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Angew. Chem. Int. Ed. [Field not mapped to EPrints] AD - Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China [Field not mapped to EPrints] AD - Laboratoire de Chimie de Coordination, CNRS, Université de Toulouse, UPS, 31077 Toulouse, France [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: active guests, coordination polymers, host-guest systems, molecular devices, spin crossover, active guests, Coordination Polymers, Host-guest system, Molecular device, Spin crossovers, Platinum, Maleic anhydride
Subjects: Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 22 Oct 2015 08:10 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/50822 (The current URI for this page, for reference purposes)
Shepherd, H.J.: https://orcid.org/0000-0003-0832-4475
  • Depositors only (login required):