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Tunable spin-crossover behavior of the hofmann-like network {Fe(bpac)[Pt(CN)4]} through host-guest chemistry

Bartual-Murgui, C., Akou, A., Shepherd, H.J., Molnár, G., Real, J.A., Salmon, L., Bousseksou, A. (2013) Tunable spin-crossover behavior of the hofmann-like network {Fe(bpac)[Pt(CN)4]} through host-guest chemistry. Chemistry - A European Journal, 19 (44). pp. 15036-15043. ISSN 09476539 (ISSN). E-ISSN 1521-3765. (doi:10.1002/chem.201300227) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:50819)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
https://doi.org/10.1002/chem.201300227

Abstract

A study of the spin-crossover (SCO) behavior of the tridimensional porous coordination polymer {Fe(bpac)[Pt(CN)4]} (bpac=bis(4-pyridyl) acetylene) on adsorption of different mono- and polyhalobenzene guest molecules is presented. The resolution of the crystal structure of {Fe(bpac)[Pt(CN) 4]}Ã?G (G=1,2,4-trichlorobenzene) shows preferential guest sites establishing Ï?Ã?Ã?Ã?Ï? stacking interactions with the host framework. These host-guest interactions may explain the relationship between the modification of the SCO behavior and both the chemical nature of the guest molecule (electronic factors) and the number of adsorbed molecules (steric factors). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type: Article
DOI/Identification number: 10.1002/chem.201300227
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Chem. Eur. J. [Field not mapped to EPrints] AD - Laboratoire de Chimie de Coordination, CNRS, Université de Toulouse (UPS, INP), 205 route de Narbonne, 31077 Toulouse, France [Field not mapped to EPrints] AD - CNRS and Université de Toulouse (UPS INSA, IAES), LAAS, 7 avenue du colonel Roche, 31077 Toulouse, France [Field not mapped to EPrints] AD - Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedratico Jose Beltran Martinez 2, 46980 Valencia, Spain [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: clathrates, host-guest systems, metal-organic frameworks, spin crossover, stacking interactions, Clathrates, Host-guest system, Metal organic framework, Spin crossovers, Stacking interaction, Chemical modification, Crystalline materials, Hydrates, Molecules, Platinum
Subjects: Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 22 Oct 2015 08:07 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/50819 (The current URI for this page, for reference purposes)
Shepherd, H.J.: https://orcid.org/0000-0003-0832-4475
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