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Ligand-directed control over crystal structures of inorganic-organic frameworks and formation of solid solutions

Yeung, H.H.-M., Li, W., Saines, P.J., Koster, T.K.J., Grey, C.P., Cheetham, A.K. (2013) Ligand-directed control over crystal structures of inorganic-organic frameworks and formation of solid solutions. Angewandte Chemie International Edition, 52 (21). pp. 5544-5547. ISSN 1433-7851. (doi:10.1002/anie.201300440) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1002/anie.201300440

Abstract

Grounded in fact: Inorganic-organic frameworks with 3D Li-O-Li connectivity can form solid solutions through mechanochemical synthesis. High-resolution synchrotron powder X-ray diffraction and cross-polarization solid-state NMR spectroscopy demonstrate complete ligand mixing in the resulting binary and ternary systems (see picture for trends in unit cell volume (V) of the ternary system {Li2(suc)x(mal)y(met)z} n).

Item Type: Article
DOI/Identification number: 10.1002/anie.201300440
Uncontrolled keywords: inorganic-organic frameworks, ligand effects, lithium, nanoindentation, solid solution, Cross polarizations, High resolution, Inorganic-organic, Ligand effect, Mechanochemical synthesis, Solid-state NMR spectroscopy, Synchrotron powder X-ray diffractions, Unit-cell volume, Lithium, Nanoindentation, Nuclear magnetic resonance spectroscopy, Solid solutions, Ternary systems, X ray diffraction, Ligands
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Paul Saines
Date Deposited: 06 Oct 2015 15:28 UTC
Last Modified: 29 May 2019 16:04 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/50720 (The current URI for this page, for reference purposes)
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