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Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization

Biagini, S.C.G., Gibson, V.C., Giles, M.R., Marshall, E.L., North, M. (2008) Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization. Journal of Polymer Science, Part A: Polymer Chemistry, 46 (24). pp. 7985-7995. ISSN 0887624X (ISSN). (doi:10.1002/pola.23098) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

The block and random copolymerization of a series of amino acid and amino ester functionalized norbornenes by ring-opening metathesis polymerization (ROMP) induced by the well-defined molybdenum [Mo(=N-2,6-iPr-C 6H3)(=CHC-Me2)Ph)(OCMe3) 2] or ruthenium [Ru(PCy)2Cl2(=CHPh)] based initiators is described. The monomers are derived from the amino acids glycine, alanine, and isoleucine or the methyl esters of these amino acids and either endo- or exo-norborn-5-ene-2,3dicarboxylic anhydride. Enantiomerically pure monomers afforded optically active polymers, and the mechanism and kinetics of the copolymerizations are investigated. © 2008 Wiley Periodicals, Inc.

Item Type: Article
DOI/Identification number: 10.1002/pola.23098
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - J Polym Sci Part A [Field not mapped to EPrints] AD - Department of Chemistry, University of Wales, Bangor, Gwynedd LL57 2UW, United Kingdom [Field not mapped to EPrints] AD - University of Kent at Canterbury, Canterbury, Kent, CT2 7NR, United Kingdom [Field not mapped to EPrints] AD - Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Rd., South Kensington, London, SW7 2AY, United Kingdom [Field not mapped to EPrints] AD - Chemical Laboratory, School of Physical Sciences, University of Kent at Canterbury, Canterbury, Kent CT2 7NR, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Amino acids, Biomimetic, Peptides, ROMP, Amination, Amino acids, Biomimetics, Chemical reactions, Copolymerization, Esterification, Esters, Functional polymers, Living polymerization, Molybdenum, Monomers, Organic acids, Organic compounds, Peptides, Polymerization, Polymers, Proteins, Ring opening polymerization, Ruthenium, Amino esters, Biomimetic, Functionalized, Mechanism and kinetics, Metathesis polymerizations, Methyl esters, Norbornenes, Optically active polymers, Random copolymerizations, ROMP, Amines
Subjects: Q Science > QD Chemistry > QD431 Organic Chemistry- Biochemistry- Proteins, peptides, amino acids
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 21 Jul 2015 10:57 UTC
Last Modified: 15 Jan 2020 04:06 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/49615 (The current URI for this page, for reference purposes)
Biagini, S.C.G.: https://orcid.org/0000-0002-4713-5127
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