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A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions

Evans, N.H., Serpell, C.J., Beer, P.D. (2011) A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions. Chemical Communications, 47 (31). pp. 8775-8777. ISSN 13597345 (ISSN). (doi:10.1039/c1cc13247d) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

A ferrocene functionalised redox-active [3]rotaxane which contains two interlocked anion recognition sites has been prepared by chloride anion templation. With chloride two equivalents of anion are bound, one in each of the interlocked cavities, while sulfate forms a 1:1 stoichimetric sandwich type complex; the rotaxane can also electrochemically sense the two anions in acetonitrile. © 2011 The Royal Society of Chemistry.

Item Type: Article
DOI/Identification number: 10.1039/c1cc13247d
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Chem. Commun. [Field not mapped to EPrints] AD - Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: acetonitrile, anion, chloride, ferrocene, rotaxane, sulfate, article, binding affinity, carbon nuclear magnetic resonance, chemical structure, crystal structure, electrochemical detection, electrospray mass spectrometry, proton nuclear magnetic resonance, stoichiometry, synthesis, X ray diffraction
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 10 Jul 2015 15:17 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/49492 (The current URI for this page, for reference purposes)
Serpell, C.J.: https://orcid.org/0000-0002-2848-9077
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