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A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

Evans, N.H., Serpell, C.J., Beer, P.D. (2011) A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology. New Journal of Chemistry, 35 (10). pp. 2047-2053. ISSN 11440546 (ISSN). (doi:10.1039/c1nj20109c) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1:1 CDCl 3:CD 3OD. © 2011 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

Item Type: Article
DOI/Identification number: 10.1039/c1nj20109c
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - New J. Chem. [Field not mapped to EPrints] AD - Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: acetic acid, anion, bromide ion, chloride ion, diamide, fluorophosphate, macrocyclic compound, meta xylene, rotaxane, solvent, article, chemical binding, priority journal, synthesis
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 10 Jul 2015 15:17 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/49491 (The current URI for this page, for reference purposes)
Serpell, C.J.: https://orcid.org/0000-0002-2848-9077
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