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Intermolecular interactions in bromo-, methyl-, and cyanoimidazole derivatives

Serpell, C.J., Beer, P.D. (2013) Intermolecular interactions in bromo-, methyl-, and cyanoimidazole derivatives. Crystal Growth and Design, 13 (7). pp. 2866-2871. ISSN 15287483 (ISSN). (doi:10.1021/cg400273p) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
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Abstract

Materials containing bistable N-H�N hydrogen bonds, such as imidazole crystals, show promise for applications in electronics. Herein, we examine the effect of imidazole functionalization upon structural parameters relating to proton transfer, molecular rotation, and order-disorder transitions. Three different substituents are studied: methyl-, bromo-, and cyano-, resulting in steric, electronic, and supramolecular modification of the imidazole core. © 2013 American Chemical Society.

Item Type: Article
DOI/Identification number: 10.1021/cg400273p
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Cryst. Growth Des. [Field not mapped to EPrints] AD - Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA, United Kingdom [Field not mapped to EPrints] AD - Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, QC, H3A 0B8, Canada [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Bistables, Cyanoimidazole, Functionalizations, Intermolecular interactions, Molecular rotations, Structural parameter, Hydrogen bonds, Molecular dynamics, Stereochemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 10 Jul 2015 15:53 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/49480 (The current URI for this page, for reference purposes)
Serpell, C.J.: https://orcid.org/0000-0002-2848-9077
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