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Formation of disordered and partially ordered LixCo 1-xO

Wu, Y., Pasero, D., McCabe, E.E., Matsushima, Y., West, A.R. (2009) Formation of disordered and partially ordered LixCo 1-xO. Journal of Materials Chemistry, 19 (10). pp. 1443-1448. ISSN 09599428 (ISSN). (doi:10.1039/b816486j) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

Analysis of XRD, TG, XANES and density measurement data show that a new, partially-ordered, rock salt-like phase, W, exists for LixCo 1-xO, 0.075 â?¤ x â?¤ 0.24(2)-0.31(2), depending on temperature, with doping mechanism: 2Co2+ â?? Li+ + Co3+. Phase W forms as ordered domains within a cation-disordered rock salt solid solution based on CoO; domain size depends on temperature and composition. Binary phase diagrams of LixCo1-xO and phase W solid solutions in air and N2 are presented. © 2009 The Royal Society of Chemistry.

Item Type: Article
DOI/Identification number: 10.1039/b816486j
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - J. Mater. Chem. [Field not mapped to EPrints] AD - Department of Engineering Materials, University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom [Field not mapped to EPrints] AD - Division of Advanced Materials Science and Technology, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei-shi, Tokyo 184-8588, Japan [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Cobalt compounds, Crystallization, Phase diagrams, Salt deposits, Solidification, Binary phase diagrams, Density measurements, Domain sizes, Doping mechanisms, Ordered domains, Rock salts, XRD, Solid solutions
Subjects: Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Emma McCabe
Date Deposited: 10 Apr 2015 10:01 UTC
Last Modified: 01 Aug 2019 10:38 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/47933 (The current URI for this page, for reference purposes)
McCabe, E.E.: https://orcid.org/0000-0001-5868-4570
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