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Sol-gel produced sodium calcium phosphosilicates for bioactive applications: Synthesis and structural characterisation

Carta, Daniela, Newport, Robert J., Knowles, J.C., Smith, M.E., Guerry, P. (2011) Sol-gel produced sodium calcium phosphosilicates for bioactive applications: Synthesis and structural characterisation. Materials Chemistry and Physics, 130 (1-2). pp. 690-696. ISSN 0254-0584. (doi:10.1016/j.matchemphys.2011.07.050) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1016/j.matchemphys.2011.07.05...

Abstract

A series of phosphosilicates P2O5 (45 mol%)–CaO (20–40 mol%)–Na2O (5–20 mol%)–SiO2 (10–15 mol%) has been synthesised by the sol–gel route using PO(OH)3−x(OC2H5)x (x = 1, 2) as the phosphorus precursor. Evolution of the gels with temperature was studied using thermogravimetric analysis and differential thermal analysis. These phosphosilicates show good stability against crystallisation remaining fully amorphous even after calcination at 400 °C. The short-range structure of the stabilised sol–gel glasses and the effect of adding modifier oxides to the network structure have been investigated using a combination of techniques: FT-IR spectroscopy, 31P magic angle spinning NMR, high energy XRD and P L-edge XANES.

Item Type: Article
DOI/Identification number: 10.1016/j.matchemphys.2011.07.050
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Mater Chem Phys [Field not mapped to EPrints] AD - School of Physical Sciences, University of Kent, Canterbury CT2 7NH, United Kingdom [Field not mapped to EPrints] AD - Eastman Dental Institute, University College London, 256 Gray's Inn Road, London WC1X 8LD, United Kingdom [Field not mapped to EPrints] AD - WCU Research Centre of Nanobiomedical Science, Dankook University, San 29, Anseo-dong, Dongnam-gu, Cheonan-si, Chungnam 330-714, South Korea [Field not mapped to EPrints] AD - Department of Physics, University of Warwick, Coventry CV4 7AL, United Kingdom [Field not mapped to EPrints] AD - Dipartimento di Scienze Chimiche, Universit di Cagliari, S.P. Monserrato-Sestu Km 0.700, I-09042 Monserrato, Cagliari, Italy [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: Phosphosilicate glasses, Sol-gel, Characterisation, FTIR spectroscopy, Good stability, High energy, Magic angle spinning NMR, Network structures, Phosphosilicate glass, Phosphosilicates, Short-range structure, Sol-gel glass, Sol-gel routes, Thermogravimetric analysis and differential thermal analysis, XANES, XRD, Calcination, Differential thermal analysis, Glass, Phosphorus, Silicon compounds, Sodium, Sol-gel process, Sol-gels, Sols, Thermogravimetric analysis, Gels
Subjects: Q Science > QC Physics > QC173.45 Condensed Matter
Q Science > QD Chemistry > QD478 Solid State Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 12 Feb 2015 14:58 UTC
Last Modified: 29 May 2019 14:09 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/46962 (The current URI for this page, for reference purposes)
Newport, Robert J.: https://orcid.org/0000-0002-2365-992X
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