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Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene

Berko, Aaron, Horton, Peter N., Hursthouse, Michael B., Packer, Robert J., Went, Michael J. (2005) Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene. Inorganic Chemistry Communications, 8 (5). pp. 488-490. ISSN 1387-7003. (doi:10.1016/j.inoche.2005.03.003) (KAR id:3765)


Base-catalysed rearrangement of 1,4,7-trithiacycloundec-9-yne affords 2,11-Divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene characterised by NMR spectroscopy and X-ray crystallography. The 18-membered macrocycle has six of the 12 C-S bonds in gauche configurations.

Item Type: Article
DOI/Identification number: 10.1016/j.inoche.2005.03.003
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User: Michael Went
Date Deposited: 30 Aug 2008 21:15 UTC
Last Modified: 16 Nov 2021 09:42 UTC
Resource URI: (The current URI for this page, for reference purposes)

University of Kent Author Information

Berko, Aaron.

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Went, Michael J..

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